Binding of periodicals

Define ‘TQM’. Discuss its application in library

 Explain the implications of ICT developments on e-procurement and e-documents.

List elements of HR planning. Explain the need for induction and deployment in libraries.

List the general principles of management. Explain how their application leads to efficiency in working of libraries

How you will introduce a formyl group into phenol ring.

Write the mechanism of Pinacol-pinacolone reaction.

Write their representative reaction for the following reactions.

(b) Sandmeyer reaction

(c) Reimer-Tiemann reaction

Mannich reaction

(d) Willgerodt reaction

(c) Knoevenagel reaction

Arrange the following in order of their increasing reactivity towards  substitution reactions: bromomethane, 1-bromo-propane, 2-bromopropane, 2-bormo-2-methyl propane. Justify your answer.

What is aldol condensation? Write its mechanism.

What would be the final products of the reaction of HI with diethyl ether and anisol? Write the mechanism of both the reactions.

Nitro group is meta directing, explain.

Discuss the role of Lewis acids in halogenations and alkylation reactions of benzene. Write the limitations of Freidel Crafts alkylation reaction.

Both 1, 3, 5-cycloheptatrienyl cation and 1,3,5-cycloheptatriene have 6  elections, comments on the aromaticity of these compounds.

Define solubility product constant and derive an expression for the solubility product constant for a sparingly soluble salt of M2A3 type having a solubility of S mol dm³.

Calculate the pH of 0.1 M aqueous solution of sodium formate at 298 K. [Given: Ka 

Explain the effect of addition of inert gas to a gaseous equilibrium reaction under the conditions of i) constant volume and ii) constant pressure.

Define degree of hydrolysis and derive its relationship with hydrolysis constant

For the following equilibrium reaction

the equilibrium concentrations are  [Show that the equilibrium will shift towards the reactants side if the concentration of SO, is suddenly doubled.

Define equilibrium constant and write the expressions for concentration equilibrium constant for the following reaction