b) Define solubility product constant and derive the relationships between solubility and solubility product constants for salts of AB2, A2B types.
Solubility product constant (Ksp) is a measure of the equilibrium solubility of an ionic compound in a particular solvent. It is the product of the concentrations of the ions in a saturated solution of the compound, with each concentration raised to the power of its stoichiometric coefficient in the balanced ____ __________ ________ ________ ___ ____ ____ ___ __________ __________ ___.
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a) In normal reaction conditions, chlorobenzene does not react with NaOH, but 1- chloro-4-nitrobenzene reacts with NaOH in these conditions. Explain.
a) Explain the effect of common ions on the ionisation equilibria of weak acids with the help of a suitable example.
b) What is reaction quotient and how is it helpful in determining the direction of a given reaction?
b) Taking suitable example write the mechanism of Mannich reaction.
b) Which one of the following would undergo faster reaction? Explain
or
a) Define and explain a thermodynamically reversible process.
b) 0.25 mol of an ideal monoatomic gas undergoes isothermal expansion from a volume of 2.0 dm3 to 10 dm3 at 27 oC. Calculate the maximum work that can be obtained from this process.
Arrange the following carbonyl compounds in the order of their favourability for formation of nitriles: