Discuss the oxidation of monoalkylacetylenes using thalium nitrate. Also give the mechanism of the reaction.
The oxidation of monoalkylacetylenes using thallium nitrate (TlNO₃) leads to the formation of α,β-unsaturated carbonyl compounds, primarily aldehydes or ketones, depending on the substituent on the alkyne. Thallium nitrate serves as a powerful oxidizing agent in this reaction due to the high oxidation _____ ______ ________ _____ _______ ____ _______.
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