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Rubredoxins are small iron-sulfur proteins that function as electron carriers in various biological redox processes. Unlike other iron-sulfur proteins such as ferredoxins, rubredoxins do not contain cluster-type Fe–S centers but instead possess a single iron atom coordinated by four cysteine residues through thiolate groups. The coordination geometry is approximately tetrahedral, giving the protein its distinctive structural and electronic properties. These __________ ______ __________ __________ ____.
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