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Dinitrogen complexes are coordination compounds in which molecular nitrogen, N₂, acts as a ligand and coordinates to a metal atom through its nitrogen lone pair. Although N₂ is chemically very stable because of its strong triple bond, it can coordinate to certain transition metals, particularly metals having suitable electron density and vacant orbitals. The most important metals forming dinitrogen complexes are those of the early and middle transition series, especially titanium, vanadium, chromium, molybdenum, tungsten, iron, ruthenium, osmium, cobalt, nickel and some of the platinum-group metals. Complexes of molybdenum, tungsten ________ _____ ________ __________ _______ ________ ___ _________ _____.
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