What are left- and right- circularly polarised lights? Draw suitable diagrams for them.
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What is the principle of microscopic reversibility? Explain taking the example of an addition-elimination reaction or a nucleophilic substitution reaction.
How are disubstituted cyclohexanes different from monosubstituted cyclohexanes with reference to the isomerism? Draw the two chair conformations for each of the following disubstituted cyclohexanes. Draw also the cis and trans isomers and indicate the more stable isomer.
i) cis-Bromo-1-methylcyclohexane
ii) trans-2-Butyl-1-isopropylcyclohexane
iii) cis-4-Ethyl-1-hydroxycyclohexane
Carry out the following conversions as indicated.
a) Fischer form to: i) Staggered and Eclipsed Sawhorse forms and
ii) Staggered and Eclipsed Newman forms
b) Flying wedge form to Fischer forms
Write the product formed and give the mechanism.
Arrange the following anions in the decreasing order of stability.
Give any two applications of ORD and CD.
What is pseudoasymmetry? Explain with the help of a suitable example.