Give the possible electronic configurations for and &n

Question

Give the possible electronic configurations for $d^{3}$ and $d^{6}$ systems in a tetrahedral crystal field.

11 Mar 2024

Answer :

Word Count : 192

In a tetrahedral crystal field, the splitting of the d orbitals results in a different electronic configuration compared to the octahedral crystal field. For d^3 and d^6 systems, here are the possible electronic configurations in a tetrahedral crystal field:

1. **d^3 system**:
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$[C1_{2}]_{0}/M$	$[NO]_{0}M$	Initial rate/ $Ms^{-1}$
0.10	0.10	$3.0\times 10^{-3}$
0.20	0.10	$6.0\times 10^{-3}$
0.20	0.20	$2.4\times 10^{-2}$