What are the possible number of isomers for the octahedral complex ion

Question

$\left [ Co(NH_{3}) C1\right ]^{+}?$

11 Mar 2024

Answer :

Word Count : 315

To determine the possible number of isomers for the octahedral complex ion $[Co(NH_3)Cl]^+$, we can analyze its structural possibilities.

In an octahedral complex, there are several possible arrangements of ligands (in this case, NH₃ and Cl⁻) around the central metal ion (Co²⁺).

The possible arrangements are:

1. All six ligands (NH₃ and Cl⁻) in cis positions.
2. All six ligands in trans positions.
3. Four ligands in equatorial positions and two ligands in axial positions.
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$[C1_{2}]_{0}/M$	$[NO]_{0}M$	Initial rate/ $Ms^{-1}$
0.10	0.10	$3.0\times 10^{-3}$
0.20	0.10	$6.0\times 10^{-3}$
0.20	0.20	$2.4\times 10^{-2}$