Which are the cases when tetrahedral geometry is favoured over octahed

Question

Which are the cases when tetrahedral geometry is favoured over octahedral geometry for metal complexes? Why are they so?

11 Mar 2024

Answer :

Word Count : 256

Tetrahedral geometry is favored over octahedral geometry in metal complexes under certain conditions, primarily due to steric factors and ligand preferences.

1. Steric Effects: When bulky ligands are present around the metal center, they may hinder the approach of additional ligands required __________ _______ _____ _________ _____ ___ ___ __________ ____.
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$[C1_{2}]_{0}/M$	$[NO]_{0}M$	Initial rate/ $Ms^{-1}$
0.10	0.10	$3.0\times 10^{-3}$
0.20	0.10	$6.0\times 10^{-3}$
0.20	0.20	$2.4\times 10^{-2}$