Question
Give an example of a transition metal-dinitrogen complex. Give suitable chemical equation for its preparation. In what fashion can the two metal atoms be bridged by dinitrogen? What happens when the dinitrogen ligands bind in side-on mode? Gives suitable diagrams.
Answer :
Word Count : 299
A transition metal-dinitrogen complex is a coordination compound in which molecular nitrogen (N₂) acts as a ligand and coordinates with a transition metal atom. A common example is the dinitrogen complex of molybdenum, ([Mo(N_2)_2(PPh_3)_2]), where nitrogen molecules are bonded to the molybdenum centre. Another important example is the bridged dinitrogen complex of cobalt, ([Co(N_2)(en)_2]_2^{2+}), in which the N₂ molecule connects two metal centres. The preparation of a transition metal-dinitrogen complex can be represented by _______ _____ __________ ____ ______ ____ ___.
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A transition metal-dinitrogen complex is a coordination compound in which molecular nitrogen (N₂) acts as a ligand and coordinates with a transition metal atom. A common example is the dinitrogen complex of molybdenum, ([Mo(N_2)_2(PPh_3)_2]), where nitrogen molecules are bonded to the molybdenum centre. Another important example is the bridged dinitrogen complex of cobalt, ([Co(N_2)(en)_2]_2^{2+}), in which the N₂ molecule connects two metal centres. The preparation of a transition metal-dinitrogen complex can be represented by _______ _____ __________ ____ ______ ____ ___.
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