Discuss the importance of cadmium of biological system. Why they cannot harm new bond babies? What is the effect of long term cadmium exposure in animals and human?
Cadmium is a heavy metal that holds significant importance in biological systems, especially in bioinorganic chemistry and toxicology. In biological systems, cadmium can mimic essential metals like zinc and calcium due to their similar chemical properties, leading to its uptake and accumulation in living organisms.
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Give the following reactions for the formation of: (i) carbonylate anion by addition of alkali or reduction (any two) (ii) carbonyl hydrides (any one) (iii) carbonyls by displacement of CO by other ligands (any two).
Give IUPAC name of the following compounds:
b) Evaluate
Explain bathochromic shift with a suitable example.
State whether the following statements are True or False? Justify your answers with the help of a short proof or a counter example: (10)
a) The function f, defined by is an odd function.
b)
c) The function f, defined by is differentiable in [0,1].
d) has no points of inflection.
e) is increasing in [− ,5 − 3].
Using Trapezoidal rule, calculate by dividing the interval ]1,0[ in 5 equal subintervals. Hence evaluate π.
If the first three non-zero terms of Maclaurin’s series for sin x are used to approximate sin show that the error is less than 1/50.