Question

Determine the equilibrium dissociation energy of CO and F2 , if the groundvibrational state dissociation energy is 11.09eV and 1.60eV for CO and F2 molecule, respectively. The fundamental vibrational frequency is 1 2170cm-1 for CO and 1 917cm-1 for F2 .

21 Apr 2025
Answer :
Word Count : 437

To determine the equilibrium dissociation energy of CO and F₂, we need to account for both the ground vibrational state dissociation energy and the zero-point energy (ZPE), which is the energy associated with the vibrational motion at the ground state. 

The formula for the ZPE is given by:

\[
E_{\text{ZPE}} = \frac{1}{2} h \nu
\]

Where \( h \) is Planck's constant, and \( \nu \) is the fundamental vibrational ___ __________ ________ ________ ___ ____ __________ _______.
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