Question
One of the three HMO molecular orbitals (MOs) for allyl radical is given below:
ψ = ½ χ₁ – (1/√2) χ₂ + ½ χ₃
Find out all three MOs of allyl radical and arrange them in order of increasing energy. Justify your answer.
Answer :
Word Count : 140
Given ψ₃ = ½χ₁ − (1/√2)χ₂ + ½χ₃, the complete Hückel set for allyl (three pz AO basis χ₁, χ₂, χ₃) is obtained from the 3×3 tridiagonal secular ___ ___ ____ ___ ______ ___ _____ ___ _________ ______ __________.
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Given ψ₃ = ½χ₁ − (1/√2)χ₂ + ½χ₃, the complete Hückel set for allyl (three pz AO basis χ₁, χ₂, χ₃) is obtained from the 3×3 tridiagonal secular ___ ___ ____ ___ ______ ___ _____ ___ _________ ______ __________.
_________ ____ ______ ________ _____ _______ ______.
_________ ________ ___ ________ ____.
_________ _______ __________ ______ _________ ______ _______ ________.
____ _____ ______ ______ ________ _____ ___ _______ ___ _______ ____ _________.
___ _____ _______ ___ ___ _________ ___ __________ ________ ______ ______ __________.
_________ _____ __________ ___ ____ _________ _________ ________ ________ _____.
___ _________ _____ ___ ___ _____ _______ ___ ________.
_____ _________ __________ _____ ________ ______ ________ __________ ___ _____.
_________ ________ ____ _______ ______ _____ _______.
________ ______ ___ _________ _____ ______ ________ _______ _______ ____.
_______ ___ ________ _______ _____ __________.
_______ _____ ______ _____ ________.
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