Question

In the determination of transference numbers of HCl by moving boundary method a 0.10 M solution of HCl was taken in a cell having uniform area of cross section of 1.6 cm2 . At the end of experiment the boundary moved by 11.7 cm and 0.22 g of silver was deposited on the cathode of silver coulometer. Calculate the transference numbers of ions of HCl.

22 Jan 2021
Answer :
Word Count : 86

Transport number of H+ ions = l x a x c / 1000Q (moving boundary method)

where,

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