Discuss Hittorf method of determination of transport numbers.
The Hittorf method is a classical technique used to determine the transport numbers of ions in an electrolyte solution. The transport number, denoted as t+t_+ for the cation and t−t_- for the anion, represents the fraction of the total current carried by each ion in an electrolytic solution. The method is based on the measurement of the change in concentration of ions near the electrodes when an ______ ____ ___ ______ ____ _________.
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