What is meant by Cluster Integrals? Express B2 and B3 in terms of Cluster Integrals.
See Answer →The susceptibility of is
and its density is
. Calculate its total polarisability. Assume that the mass number for
is 32.
In an n-type semiconductor the Fermi level lies below the conduction band at
. Calculate the position of the Fermi level when the temperature is raised to
.
State the Virial theorem and prove Boyle’s law using it.
See Answer →Calculate the resistivity of Silicon at given that its resistivity at
is
.
What is the Bose-Einstein condensation? Write an expression of number of particles in the excited state (Nex) in terms of Bose-Einstein condensation temperature (Tc), total number of bosons (N) in an assembly and temperature T. Show a plot of distribution of bosons as a function of temperature below and above the Tc.
See Answer →Calculate the energy dispersion for s-band in the bcc lattice for the tight binding approximation.
Note: For the central atom located at (0,0,0) in the bcc unit cell, the nearest neighbours are located at , where a is the lattice constant.
Show that the probability that a state with energy above the Fermi level
filled is equal to the probability of a state with energy
below the Fermi level
is empty.
Using the relation of thermodynamic probability
Obtain an expression of Fermi Dirac distribution function. Show a plot of (the occupation index of a state corresponding to energy
) versus
for different temperatures and discuss it. What is the physical interpretation of Fermi energy?
For the energy dispersion relation:
calculate the inverse mass tensor.
State and prove quantum Liouville equation.
See Answer →The time evolution of the quantum state, is given by the Schrödinger wave equation:
where H is the Hamiltonian operator. Using this equation, obtain time evolution of the wave function when the energy eigenvalue is E.
See Answer →In Sommerfeld free electron theory, show that at a temperature T
(i) and (ii)
The time evolution of the quantum state, is given by the Schrödinger wave equation:
A proton inside a nucleus
may have speed upto
. How many quantum states are available to it?
A divalent metal crystallizes in an fcc structure with a lattice constant of 4.5 A. Calculate the number density of conduction electrons and the Fermi velocity.
See Answer →For the grand canonical ensemble, obtain an expression for the ensemble average energy and ensemble average particle numbers.
See Answer →Calculate the temperature at which the lattice contribution to the specific heat and the electronic contribution to the specific heat become equal in a metal which has a Debye temperature of and a Fermi energy
.
For a linear chain of identical atoms of mass calculate the maximum value of the angular frequency of the longitudinal wave and the group velocity at
, given that the inter-atomic distance is 2.0 A and the spring constant is
.
Obtain expression for average energy for the canonical ensemble in terms of partition function Z.