Schmidt rearrangement

Curtius rearrnagement

What is Rosenmund reduction? Give an appropriate example for this reaction.

Arrange the different carboxylic acid derivatives in the decreasing order of their reactivity towards nucleophilic substituted reactions and give reason for your answer.

. Explain the mechanism of Fischer esterfication reaction.

Briefly explain the process of electrolysis.

Discuss any two applications of electrolysis.

 What is quinhydrone electrode? Give its advantageous and disadvantageous.

 Give an example of a concentration cell with transference.

 What are the functions of a salt bridge?

Draw the schematic diagram of a Daniell cell and give the reactions taking place at the electrodes.

 List the applications of conductivity measurement.

 Explain ionic mobility and give its units. Briefly explain the factors affecting it.

The conductivity of a 0.1 M aqueous solution of acetic acid is found to be 5.3 x 104S cm. Calculate the molar conductivity of acetic acid solution at the given concentration.

Define conductivity and give its units.

 Draw and explain the phase diagram of water highlighting its important features.

Write the integrated form of Clausius-Clapeyron equation. What were the two assumptions made by Clausius?

 Define the following terms:

(i) Phase

(ii) Components

(iii) Degrees of freedom

) Discuss the effect of impurities on CST values.

 Draw and explain the mutual miscibility curve for phenol - water system.