A population of single-celled organisms was grown in a Petri dish over a period of 24 hours. The number of organisms at a given time is recorded in the table below. Fit the data in the table below to an exponential model :
| x (time in hours) | 0 | 4 | 8 | 12 | 16 | 20 | 24 |
| y | 25 | 36 | 52 | 68 | 85 | 104 | 142 |
The rotational constant for the excited electronic state of a particular molecule is 20% smaller as compared to the rotational constant of its ground electronic state. Determine the values for the first 15 lines of the R-branch. Discuss the variation of the separation between successive transition lines of this branch.
See Answer →The HCl molecule shows its first and second overtone transitions at and
, respectively. Assuming anharmonic oscillator model, determine the anharmonicity constant, the equilibrium vibrational frequency, zero point energy, and the force constant of this molecule.
What are the advantages and drawbacks of the Secant method when compared to the Bisection Method and the Newton-Raphson Method?
See Answer →Write the Hamiltonian of a multi-electron atom. Obtain an expression for the effective potential experienced by an electron of this atom under the central field approximation.
See Answer → Use the Secant method with initial guesses of and
to calculate the root/s of the equation
up to three iterations. Calculate the absolute relative approximate error at each stage.
Explain why a polynomial is a useful choice for an interpolating function.
See Answer →The series for ex can be written as:
Calculate the truncation error when the first four terms of the series are used to evaluate e1.5.
Explain round-off error and truncation error, with one example of each.
See Answer →Using molecular orbital method, construct all pssible trial wavefunctions (including spin) for a diatomic molecule. Of these functions, which trial function is expected to have the minimum energy? Give justification for your answer.
See Answer →Using Thomas-Fermi method, derive an expression for the total kinetic energy of N electrons in a cubic box of side L, and hence obtain the expression for pressure.
See Answer →The anti-symmetric spin function for a two electron system is given as:$
Prove that is an eigenfunction of
.
Consider K meson of mass mK decaying into two pions of mass each, in the laboratory frame. Show that the energy of each pion is equal to
and the momenta are
.
a) Determine the shift in energy caused by relativistic correction to kinetic energy for and
levels of hydrogen atom. Using appropriate selection rules, show which transitions are allowed.
Write down the wave function for . Use the isospin raising operator to derive the wavefunctions for
and
.
From the isospin and hypercharge assignment show that the t and b quarks have charges +2/3 and -1/3 respectively.
See Answer →Explain why we must define an intrinsic parity for each particle.
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Explain the working of organic LED.
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