With the help of suitable equations, give any two methods for preparation of metal carbonyls by reductive carbonylation. 

Reductive carbonylation is a method used to synthesize metal carbonyl complexes, where a metal reacts with carbon monoxide (CO) under reducing conditions. Below are two common methods for the preparation of metal carbonyls via reductive carbonylation:

1. Reaction of Metal Halides with Carbon Monoxide in ___ __________ ____ ___ __________ _______ _________.
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