Explain the principle for the experimental determination of activity and activity coefficient from solubility measurements.

The activity and activity coefficient of a solute in a solution can be experimentally determined using solubility measurements based on thermodynamic principles. The solubility of a slightly soluble salt in a solvent is governed by its equilibrium with ___ ________ ____ _________ ______ _______ _____ __________ _______ __________ ___ ________.
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