Explain the origin of Raman spectrum in terms of quantum theory of radiation. State the "Rule of mutual exclusion'. What is its significance?
The Raman spectrum originates from the inelastic scattering of photons by molecules, a phenomenon described by quantum theory. When light interacts with matter, most of the photons are elastically scattered (Rayleigh scattering), retaining their energy. However, a small fraction of photons undergo inelastic scattering, resulting in a shift in their frequency. This shift corresponds to the energy difference between the initial and final vibrational states of the molecule. _____ _________ _______ __________ _____ ____ ____ _______ _______.
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