Question

Determine the number and symmetry designations of the infrared-active C-O modes in the following derivatives of Mo(CO)6-

Mo(CO)5PR3

cis-Mo(CO)4 (PR3)2

trans-MO(CO)4 (PR3)2

fac-Mo(CO)3 (PR3)3

13 Feb 2025
Answer :
Word Count : 81
  1. Mo(CO)₅PR₃:

    • This complex has C₄v symmetry.
    • The CO stretching vibrations _______ _________ _____ ___ __________ ___ ____ ___ _______.
      __________ _____ ____ _____ _____.
      ____ ____ _________ ____ _____ _______ __________ __________ ________ __________ __________.
      _____ ___ ______ ___ __________ _______ ___ ______ _____ __________ ___.
      _____ _____ ________ _________ ______ ____.
      __________ ____ __________ _____ ______.
      ________ _________ ____ ___ ______ ____ ________ ________ _________ ______ __________.
      ________ _________ __________ _________ ________ _________.
      ____ _____ ____ ________.
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