Question

Determine the number and symmetry designations of the infrared-active C-O modes in the following derivatives of Mo(CO)6-

Mo(CO)5PR3

cis-Mo(CO)4 (PR3)2

trans-MO(CO)4 (PR3)2

fac-Mo(CO)3 (PR3)3

13 Feb 2025
Answer :
Word Count : 81
  1. Mo(CO)₅PR₃:

    • This complex has C₄v symmetry.
    • The CO stretching vibrations split into A₁ _______ ___ _______ _________ __________ ___ _________ _______ _________ __________.
      ___ ___ ____ _________ ___ _____ _________ ________ ____ _____ __________.
      _______ _______ __________ _____ ______ ____ ____ ________ __________.
      __________ ___ ______ __________ ______ _________ ______ _______ _______ ___.
      __________ ________ _______ _______ ____ _______ __________ _______.
      ________ ________ _________ __________ ___ _____ ______ ______ _______.
      __________ _______ _______ _____ ____ _________ _____ ______.
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