Define thermodynamic probability of a macrostate. Establish the Boltzmann relation between entropy and thermodynamic probability.
S = kB lnW.
In statistical mechanics, the thermodynamic probability of a macrostate refers to the number of possible microscopic configurations (or microstates) that correspond to a given macrostate. A macrostate is characterized by macroscopic quantities such as temperature, pressure, volume, and energy, and the thermodynamic probability quantifies the number ______ ____ ______ __________ _______ _________ __________ ____.
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