Define critical constants and give their expressions in terms of van der Waals constants. 

Critical constants refer to the temperature, pressure, and volume at which a substance undergoes a phase transition between liquid and gas, and at this point, the liquid and gas phases become indistinguishable. These constants are essential for understanding the behavior __________ _____ ______ ___ _________ _______ _______ ______ ___ ______ _______.
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